Could tectonic processes in the early Earth have contributed to the rise of oxygen?
Twenty-one per cent of the atmosphere consists of this life-giving element. But in the deep past — as far back as the Neoarchean era 2.8 to 2.5 billion years ago — this oxygen was almost absent.Our research, published in Nature Geoscience, adds a tantalizing new possibility: that at least some of the Earth’s early oxygen came from a tectonic source via the movement and destruction of the Earth’s crust.
One feature of modern subduction zones is their association with oxidized magmas. These magmas are formed when oxidized sediments and bottom waters — cold, dense water near the ocean floor — are introduced into the Earth’s mantle. This produces magmas with high oxygen and water contents. So, we decided to look at the mineral apatite which is present in the zircon crystals in these rocks. Zircon crystals can withstand the intense temperatures and pressures of the post-crystallization events. They retain clues about the environments in which they were originally formed and provide precise ages for the rocks themselves.
These new findings indicate that oxidized magmas did form in the Neoarchean era 2.7 billion years ago. The data show that the lack of dissolved oxygen in the Archean ocean reservoirs did not prevent the formation of sulfur-rich, oxidized magmas in the subduction zones. The oxygen in these magmas must have come from another source, and was ultimately released into the atmosphere during volcanic eruptions.
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